From: Subject: METHYL ETHYL KETONE Date: Sat, 9 Dec 2006 11:40:23 -0600 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_0000_01C71B86.D0084900" X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2900.2962 This is a multi-part message in MIME format. ------=_NextPart_000_0000_01C71B86.D0084900 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.jtbaker.com/msds/englishhtml/m4628.htm METHYL ETHYL KETONE

MSDS Number: M4628 * * * * * Effective Date: 08/17/05 * = * * * *=20 Supercedes: 07/07/04

METHYL ETHYL KETONE

1. Product Identification

Synonyms: 2-Butanone; ethyl methyl ketone; MEK; = Methyl=20 acetone
CAS No.: 78-93-3
Molecular Weight: 72.11 =
Chemical Formula: CH3COCH2CH3
Product Codes: =
J.T.=20 Baker: 5385, 9214, 9319, 9323, 9414, Q531
Mallinckrodt: 6206, = 6233, 6240,=20 6243

2. Composition/Information on Ingredients

  Ingredient  =
                              CAS No         Percent        Hazardous    =
                             =20
  ---------------------------------------   ------------   ------------  =
 ---------  =20
=20
  Methyl Ethyl Ketone                       78-93-3          99 - 100%   =
    Yes                                                                  =
 =20
=20

3. Hazards Identification

Emergency Overview
--------------------------=20
DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE = FLASH=20 FIRE. HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED = THROUGH=20 SKIN. AFFECTS CENTRAL NERVOUS SYSTEM. CAUSES IRRITATION TO SKIN, EYES = AND=20 RESPIRATORY TRACT.

SAF-T-DATA^(tm) = Ratings=20 (Provided here for your convenience)=20 =
---------------------------------------------------------------------= --------------------------------------=20
Health Rating: 2 - Moderate (Life)
Flammability Rating: 3 - = Severe=20 (Flammable)
Reactivity Rating: 1 - Slight
Contact Rating: 2 - = Moderate=20
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; = VENT=20 HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red=20 (Flammable)=20 =
---------------------------------------------------------------------= --------------------------------------=20

Potential Health Effects =
----------------------------------=20

Inhalation:
Causes irritation to the nose and = throat.=20 Concentrations above the TLV may cause headache, dizziness, nausea, = shortness=20 of breath, and vomiting. Higher concentrations may cause central = nervous=20 system depression and unconsciousness.
Ingestion:
May = produce=20 abdominal pain, nausea. Aspiration into lungs can produce severe lung = damage=20 and is a medical emergency. Other symptoms expected to parallel = inhalation.=20
Skin Contact:
Causes irritation to skin. Symptoms = include=20 redness, itching, and pain. May be absorbed through the skin with = possible=20 systemic effects.
Eye Contact:
Vapors are irritating to = the=20 eyes. Splashes can produce painful irritation and eye damage. =
Chronic=20 Exposure:
Prolonged skin contact may defat the skin and = produce=20 dermatitis. Chronic exposure may cause central nervous system effects. =
Aggravation of Pre-existing Conditions:
Persons with=20 pre-existing skin disorders or eye problems or impaired respiratory = function=20 may be more susceptible to the effects of the substance.

4. First Aid Measures

Inhalation:
Remove to fresh air. If not = breathing, give=20 artificial respiration. If breathing is difficult, give oxygen. Get = medical=20 attention.
Ingestion:
Aspiration hazard. If swallowed, = vomiting=20 may occur spontaneously, but DO NOT INDUCE. If vomiting occurs, keep = head=20 below hips to prevent aspiration into lungs. Never give anything by = mouth to=20 an unconscious person. Call a physician immediately.
Skin = Contact:=20
Immediately flush skin with plenty of soap and water for at least = 15=20 minutes while removing contaminated clothing and shoes. Get medical = attention.=20 Wash clothing before reuse. Thoroughly clean shoes before reuse. =
Eye=20 Contact:
Immediately flush eyes with plenty of water for at = least 15=20 minutes, lifting upper and lower eyelids occasionally. Get medical = attention.=20

5. Fire Fighting Measures

Fire:
Flash point: -9C (16F) CC
Autoignition=20 temperature: 404C (759F)
Flammable limits in air % by volume: =
lel: 1.4;=20 uel: 11.4
Extremely Flammable.
Explosion:
Above = flash point,=20 vapor-air mixtures are explosive within flammable limits noted above. = Vapors=20 can flow along surfaces to distant ignition source and flash back. = Contact=20 with strong oxidizers may cause fire. Sealed containers may rupture = when=20 heated. Sensitive to static discharge.
Fire Extinguishing = Media:=20
Dry chemical, foam or carbon dioxide. Water spray may be used to = keep fire=20 exposed containers cool, dilute spills to nonflammable mixtures, = protect=20 personnel attempting to stop leak and disperse vapors.
Special=20 Information:
In the event of a fire, wear full protective = clothing and=20 NIOSH-approved self-contained breathing apparatus with full facepiece = operated=20 in the pressure demand or other positive pressure mode. This highly = flammable=20 liquid must be kept from sparks, open flame, hot surfaces, and all = sources of=20 heat and ignition.

6. Accidental Release Measures

Ventilate area of leak or spill. Remove all sources of = ignition.=20 Wear appropriate personal protective equipment as specified in Section = 8.=20 Isolate hazard area. Keep unnecessary and unprotected personnel from = entering.=20 Contain and recover liquid when possible. Use non-sparking tools and=20 equipment. Collect liquid in an appropriate container or absorb with = an inert=20 material (e. g., vermiculite, dry sand, earth), and place in a = chemical waste=20 container. Do not use combustible materials, such as saw dust. Do not = flush to=20 sewer! If a leak or spill has not ignited, use water spray to disperse = the=20 vapors, to protect personnel attempting to stop leak, and to flush = spills away=20 from exposures. US Regulations (CERCLA) require reporting spills and = releases=20 to soil, water and air in excess of reportable quantities. The toll = free=20 number for the US Coast Guard National Response Center is (800)=20 424-8802.

J. T. Baker SOLUSORB=AE solvent adsorbent is = recommended=20 for spills of this product.

7. Handling and Storage

Protect against physical damage. Store in a cool, dry=20 well-ventilated location, away from any area where the fire hazard may = be=20 acute. Outside or detached storage is preferred. Separate from = incompatibles.=20 Containers should be bonded and grounded for transfers to avoid static = sparks.=20 Storage and use areas should be No Smoking areas. Use non-sparking = type tools=20 and equipment, including explosion proof ventilation. Containers of = this=20 material may be hazardous when empty since they retain product = residues=20 (vapors, liquid); observe all warnings and precautions listed for the = product.=20

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
-OSHA Permissible = Exposure=20 Limit (PEL):
200 ppm (TWA)

-ACGIH Threshold Limit Value=20 (TLV):
200 ppm (TWA), 300 ppm (STEL)
Ventilation System: =
A=20 system of local and/or general exhaust is recommended to keep employee = exposures below the Airborne Exposure Limits. Local exhaust = ventilation is=20 generally preferred because it can control the emissions of the = contaminant at=20 its source, preventing dispersion of it into the general work area. = Please=20 refer to the ACGIH document, Industrial Ventilation, A Manual of=20 Recommended Practices, most recent edition, for details. Use=20 explosion-proof equipment.
Personal Respirators (NIOSH = Approved):=20
If the exposure limit is exceeded and engineering controls are not = feasible, a full facepiece respirator with organic vapor cartridge may = be worn=20 up to 50 times the exposure limit or the maximum use concentration = specified=20 by the appropriate regulatory agency or respirator supplier, whichever = is=20 lowest. For emergencies or instances where the exposure levels are not = known,=20 use a full-facepiece positive-pressure, air-supplied respirator. = WARNING: Air=20 purifying respirators do not protect workers in oxygen-deficient = atmospheres.=20
Skin Protection:
Wear impervious protective clothing, = including=20 boots, gloves, lab coat, apron or coveralls, as appropriate, to = prevent skin=20 contact. Butyl rubber is a suitable material for personal protective=20 equipment.
Eye Protection:
Use chemical safety goggles = and/or a=20 full face shield where splashing is possible. Maintain eye wash = fountain and=20 quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Clear, colorless liquid. =
Odor:=20
Sharp mint-like odor.
Solubility:
29 g in 100 g of = water.=20
Specific Gravity:
0.81 @ 20C/4C
pH:
No=20 information found.
% Volatiles by volume @ 21C (70F): =
100=20
Boiling Point:
80C (176F)
Melting Point: =
-86C=20 (-123F)
Vapor Density (Air=3D1):
2.5
Vapor = Pressure (mm=20 Hg):
78 @ 20C (68F)
Evaporation Rate (BuAc=3D1): =
2.7=20 (Ether =3D 1)

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of = use and=20 storage.
Hazardous Decomposition Products:
Carbon = dioxide and=20 carbon monoxide may form when heated to decomposition. =
Hazardous=20 Polymerization:
Will not occur.
Incompatibilities:=20
Oxidizing materials, caustics, amines, ammonia, strong bases, = chloroform,=20 chlorosulfonic acid, oleum, potassium-t-butoxide, heat or flame, = hydrogen=20 peroxide, nitric acid. Can attack many plastics, resins and rubber.=20
Conditions to Avoid:
Heat, flames, ignition sources and = incompatibles.

11. Toxicological Information

Toxicological Data:
Oral rat LD50: 2737 mg/kg;=20 inhalation rat LC50: 23,500 mg/m3/8-hr; skin rabbit LD50: 6480 mg/kg;=20 investigated as a mutagen, reproductive effector.
Reproductive=20 Toxicity:
Has shown teratogenic effects in laboratory animals. =

  --------\Cancer =
Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC =
Category
  ------------------------------------   -----    -----------    =
-------------
  Methyl Ethyl Ketone (78-93-3)           No          No            None

12. Ecological Information

Environmental Fate:
When released into the soil, = this=20 material may leach into groundwater. When released into the soil, this = material may evaporate to a moderate extent. When released into water, = this=20 material may biodegrade to a moderate extent. When released into = water, this=20 material may evaporate to a moderate extent. When released into water, = this=20 material is expected to have a half-life between 10 and 30 days. This = material=20 is not expected to significantly bioaccumulate. When released into the = air,=20 this material is expected to be readily degraded by reaction with=20 photochemically produced hydroxyl radicals. When released into the = air, this=20 material is expected to have a half-life between 1 and 10 days.=20
Environmental Toxicity:
This material is not expected = to be=20 toxic to aquatic life. The LC50/96-hour values for fish are over 100 = mg/l.=20

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be = handled as hazardous waste and sent to a RCRA approved incinerator or = disposed=20 in a RCRA approved waste facility. Processing, use or contamination of = this=20 product may change the waste management options. State and local = disposal=20 regulations may differ from federal disposal regulations. Dispose of = container=20 and unused contents in accordance with federal, state and local = requirements.=20

14. Transport Information

Domestic (Land, D.O.T.)
-----------------------=20
Proper Shipping Name: ETHYL METHYL KETONE
Hazard = Class:=20 3
UN/NA: UN1193
Packing Group: II
Information = reported=20 for product/size: 366LB

International (Water, = I.M.O.)=20
-----------------------------
Proper Shipping Name: = ETHYL=20 METHYL KETONE
Hazard Class: 3
UN/NA: UN1193 =
Packing=20 Group: II
Information reported for product/size: 366LB=20

15. Regulatory Information

  --------\Chemical Inventory Status - =
Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  =
Australia
  -----------------------------------------------  ----  ---  -----  =
---------
  Methyl Ethyl Ketone (78-93-3)                     Yes  Yes   Yes      =
Yes                                     =20
=20
  --------\Chemical Inventory Status - Part =
2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  =
Phil.
  -----------------------------------------------  -----  ---   ----  =
-----
  Methyl Ethyl Ketone (78-93-3)                     Yes   Yes   No     =
Yes         =20
=20
  --------\Federal, State & International Regulations - Part =
1\----------------
                                             -SARA 302-    ------SARA =
313------
  Ingredient                                 RQ    TPQ     List  =
Chemical Catg.
  -----------------------------------------  ---   -----   ----  =
--------------
  Methyl Ethyl Ketone (78-93-3)              No    No      Yes        No
=20
  --------\Federal, State & International Regulations - Part =
2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)=20
  -----------------------------------------  ------     ------    ------
  Methyl Ethyl Ketone (78-93-3)              5000       U159       No    =
   =20
=20
=20
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  Yes
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: Yes Pressure: No
Reactivity: No          (Pure / Liquid)

Australian Hazchem Code: 2[Y]E
Poison=20 Schedule: S5
WHMIS:
This MSDS has been prepared = according=20 to the hazard criteria of the Controlled Products Regulations (CPR) = and the=20 MSDS contains all of the information required by the CPR. =

16. Other Information

NFPA Ratings: Health: 1 Flammability: 3 = Reactivity: 0
Label Hazard Warning:
DANGER! = EXTREMELY=20 FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL OR = FATAL IF=20 SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. AFFECTS = CENTRAL=20 NERVOUS SYSTEM. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. =
Label Precautions:
Keep away from heat, sparks and=20 flame.
Keep container closed.
Use only with adequate=20 ventilation.
Wash thoroughly after handling.
Avoid breathing=20 vapor.
Avoid contact with eyes, skin and clothing.
Label = First=20 Aid:
Aspiration hazard. If swallowed, vomiting may occur=20 spontaneously, but DO NOT INDUCE. If vomiting occurs, keep head below = hips to=20 prevent aspiration into lungs. Never give anything by mouth to an = unconscious=20 person. In case of contact, immediately flush eyes or skin with plenty = of=20 water for at least 15 minutes while removing contaminated clothing and = shoes.=20 Wash clothing before reuse. If inhaled, remove to fresh air. If not = breathing,=20 give artificial respiration. If breathing is difficult, give oxygen. = In all=20 cases, get medical attention.
Product Use:
Laboratory = Reagent.=20
Revision Information:
MSDS Section(s) changed since = last=20 revision of document include: 3.
Disclaimer:=20 =
*********************************************************************= ***************************=20
Mallinckrodt Baker, Inc. provides the information contained = herein in=20 good faith but makes no representation as to its comprehensiveness or=20 accuracy. This document is intended only as a guide to the appropriate = precautionary handling of the material by a properly trained person = using this=20 product. Individuals receiving the information must exercise their = independent=20 judgment in determining its appropriateness for a particular purpose.=20 MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, = EITHER=20 EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF=20 MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE=20 INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION = REFERS.=20 ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR = DAMAGES=20 RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.=20 =
*********************************************************************= ***************************=20
Prepared by: Environmental Health & Safety
Phone = Number:=20 (314) 654-1600 (U.S.A.)

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